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Author Topic: Is hydrogen the answer?  (Read 2159 times)

Offline Wizzo

Is hydrogen the answer?
« on: October 30, 2007, 10:37:27 AM »

It’s the most commonly-occurring element in the universe, it can be burned in a combustion engine or used to fuel electric motors, and it’s vastly cleaner emissions-wise than gasoline. The automotive industry seems to have settled on hydrogen as the magic bullet solution to the looming energy crisis, and each year we see a number of fuel cell concept cars showcased by the major manufacturers – but it’s a technology with some serious hurdles to overcome before it becomes viable.

Honda is one of many major auto companies that think so – stating in a recent release on their FCX concept that “Hydrogen will fuel the next generation of global vehicles. It’s a fact accepted by the entire industry. And given that it’s the most commonly-occurring element in the universe, supply is not an issue.”

But what about the new and coming generations of plug-in electric vehicles? As with Hydrogen fuel cell vehicles, its early days yet, but pure electric vehicles seem to have a few strong points of their own. So, with a focus on fuel cells rather than hydrogen fueled internal combustion engines, let’s take a look at the set of requirements a transportation fuel source has to meet to be viable, and see how hydrogen and batteries compare:

1) Abundance – it won’t be too long before there’s a billion passenger cars on Earth, so any future-focused fuel system needs to be able to satisfy an enormous demand. There’s plenty of Hydrogen about and we’re certainly not in any shortage of electrons. Hydrogen storage and battery materials are many and varied, and lithium, the current leader in battery technology, is abundant. The two technologies are relatively even here.

2) Efficiency – Both hydrogen and batteries can be viewed as means for storing and transporting energy for later use. Thus, the ratio of how much energy you get out to what you put in is an important consideration.

Electrolysis of water is the easiest method for producing hydrogen – but only about 70% of the electric power used in the process gets stored in the hydrogen it creates. Hydrogen then needs to be either compressed or cooled to a liquid in order to store large enough volumes to be useful in a car – gas compression is the more efficient of the two processes, but still costs a further 10% of the stored energy. The efficiency of the fuel cell storage unit itself is realistically estimated at around 36% under normal driving load – leading to a dismal overall power-grid-to-wheels efficiency of less than 25%. That is, less than a quarter of the power used to produce the hydrogen is ever actually used to propel the car.

Batteries are a clear winner in the grid-to-wheels efficiency battle. Conventional Lithium-ion batteries charge at about 93% efficiency and operate at about the same efficiency, leading to an overall efficiency of over 85%. For the same energy input, you’ll get three times the power out of a battery than out of a fuel cell.

3) Safety – High pressure storage, flammability, toxicity and explosive potential all represent safety hazards. Fuel cells either contain compressed gas at up to 35MPa or liquid hydrogen which needs to be kept under -253 degrees Celsius, so there’s clearly the chance for it to cause plenty of mischief in case of an accident. Batteries, however, also have their drawbacks here, introducing the risk of electrical hazards, toxic chemicals, electrical fires and fumes. The jury’s still out on this one.

4) Refueling practicality – Does the energy source fit in with a convenient and simple usage cycle? Here is a key advantage for Hydrogen, at least in the consumer’s eyes. Because it can be stored as a liquid or gas (like gasoline or LPG), hydrogen supports the current model of refueling reasonably quickly through an exchange of fluids at a gas station. Battery electric vehicles need to be plugged in and charged, which generally takes a longer period of time. As such, they may be appropriate for daily commuting, allowing for a convenient charge overnight, but they can’t currently be quickly recharged in the same way a gasoline or hydrogen car can.

While battery technology is improving and quick-charge cells are under development, the “liquid battery” represented by hydrogen is currently a clear winner on this front.

5) Environmental factors – while both fuel cell and battery-electric engines are themselves extremely environmentally neutral, it must be noted that the production of the energy used to charge them is currently predominantly fossil fuel-based. Additionally, there are some environmental concerns inherent in the construction and disposal of batteries. Fuel cells would lead by a narrow margin, if it weren’t for the fact that they’re so inefficient that they use three times as much primary energy, and thus are responsible for three times the primary emissions. Of course, both vehicle types will still be responsible for considerable amounts of atmospheric emissions until global power grids are powered by clean and renewable energy sources.

6) Economics – Both fuel cells and high-output battery cells are currently quite expensive, although this is forecast to become less of a factor with the advent of volume production. Of greater concern are the economics of building a delivery network. The current electricity grid system is well established in most countries, and with some modification and reinforcement could be upgraded to handle the strain of fulfilling the shortage of energy left if gasoline is removed from the passenger transport equation.

Hydrogen is more problematic. To derive its main benefit – the ability to fill a car quickly with fluid energy – a hydrogen distribution network similar to that used to distribute gasoline would need to be built. Hydrogen atoms are so small that they can sneak out through the molecular structure of many containers and pipes, meaning that it’s expensive and problematic to transport in great quantities. Generating the hydrogen on-site at filling stations is a potential solution, but at the end of the day, a fully functioning hydrogen economy capable of replacing the petroleum economy will cost trillions of dollars in America alone. Battery-electrics are a clear winner in this context.

While this is certainly a simplistic overview of the two technologies, it highlights the fact that the case for battery-electric vehicles is as least as strong as for hydrogen fuel cells, if not stronger on grounds of energy efficiency and ease of distribution.

A hydrogen-based fuel economy would certainly suit the retail end of the petroleum industry, as petrol stations would be the logical distribution outlets for another form of liquid fuel, while plug-in battery electrics completely eliminate them from the energy supply chain apart from top-ups in the middle of a long trip. Does this contribute to the major automobile companies’ motives for choosing hydrogen over battery-electric?

Either way, vehicle development moves on, with Honda announcing this week that both its fuel cell FCX and a hybrid based on their CR-Z concept will go into production in 2008/9. The immediate future will encompass hybrids, plug-in electrics, and fuel cell vehicles as alternatives to petrol and diesel – but it's not yet clear which will emerge as the dominant technology.



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Wizzo

Offline Steven Roy

Re: Is hydrogen the answer?
« Reply #1 on: October 30, 2007, 01:07:55 PM »
Interesting stuff Wiz.  For me the big advantage of hydrogen over battery power is in long distance journeys.  If you are doing a 20 or 30 mile round trip each day then batteries will be fine(given a few years development).  However if you plan to do several hundred miles in a day and have to stop to re-fuel along the way I cannot see batteries working.

Who knows in 30 years we may be watching which GP team can change its batteries the quickest.

Online cosworth151

Re: Is hydrogen the answer?
« Reply #2 on: October 30, 2007, 02:46:04 PM »
The state of California has started a pilot project to build a hydrogen infrastracture:

http://www.hydrogen.energy.gov/pdfs/review06/tv_11_pedersen.pdf

It will be interesting to see how it pans out. Air Products is an nationwide industrial gasses operation.
“You can search the world over for the finer things, but you won't find a match for the American road and the creatures that live on it.”
― Bob Dylan

 


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